Structure-inheriting solid-state reactions under hydrothermal conditions

✍ Scribed by Kazuo Eda; Yuichi Uno; Noriko Nagai; Noriyuki Sotani; Chen Chen; M. Stanley Whittingham

• Publisher: Elsevier Science
• Year: 2006
• Tongue: English
• Weight: 535 KB
• Volume: 179
• Category: Article
• ISSN: 0022-4596
• DOI: 10.1016/j.jssc.2006.01.060

✦ Synopsis

We have explored several structure-inheriting solid-state reactions (SISSRs) under hydrothermal conditions for syntheses in the Co-Mo-O system. And we found an interesting hydrothermal SISSR from CoMoO 4 Á 3/4H 2 O to high-pressure (hp-) phase of CoMoO 4 , which enabled us to considerably reduce the severe conditions for the synthesis of hp-CoMoO 4 . As similar hydrothermal SISSRs are expected to be useful tools for material syntheses, we also briefly discuss them as a means of developing novel material syntheses and designs.