Substituted 2,6-octadien-4-ynedial derivatives were synthesized, which give cyclopenta[b]thiapyran or cyclopenta[b]pyran derivatives by intramolecular cyclization. During the course of studies on dehydroannulenesl), we have investigated the synthesis of substituted octadienynedial derivatives which
โฆ LIBER โฆ
Structure determinations of cyclopenta[b]thiapyrans
โ Scribed by Yasuyoshi Hasegawa; Yasushi Kai; Kunio Miki; Nobuo Tanaka; Nobutami Kasai; Yoshio Aso; Masahiko Iyoda; Masazumi Nakagawa
- Book ID
- 104234160
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 255 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
The detailedImolecular structures of substituted cyclopenta[b]thiapyrans were studied by means of H-NMR spectroscopy and X-ray diffraction method. In the preceeding paper, we reported acid-catalyzed intramolecular cyclization of 2,6-octadiene-4-ynedial derivatives to substituted cyclopenta[b]thiapyrans (J,, g, and 2).
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