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Structure determination of the three disulfide bond isomers of α-conotoxin GI: a model for the role of disulfide bonds in structural stability

✍ Scribed by John Gehrmann; Paul F. Alewood; David J. Craik

Book ID
115628494
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
614 KB
Volume
278
Category
Article
ISSN
0022-2836

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A method for the one-pot regioselective
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✍ Alan Cuthbertson; Bård Indrevoll 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 78 KB

A one-pot method for the regioselective formation of the disulfide bridges of α-conotoxin SI employing temperature-controlled orthogonal protecting groups is reported. The pairing of t-butyl and 4-methylbenzyl sidechain protecting groups was chosen for the four cysteine residues. Cleavage of the pep