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Structure Determination and Relative Properties of Novel Cubic Borates MM′4(BO3)3 (M: Li, M′: Sr; M: Na, M′: Sr, Ba).

✍ Scribed by L. Wu; X. L. Chen; H. Li; M. He; Y. P. Xu; X. Z. Li

Publisher
John Wiley and Sons
Year
2005
Weight
10 KB
Volume
36
Category
Article
ISSN
0931-7597

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The isotypic compounds Na 2 Ba 3 Sb 4 and Na 2 Sr 3 Sb 4 were prepared by the direct fusion of elements at 7503C followed by slow cooling to, and annealing at, 3003C. These crystallize in the orthorhombic system, space group Pnma (No. 62), with respective lattice dimensions of a ‫؍‬ 8.220(1), 7.919(