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Structure, crystal chemistry and thermal evolution of the δ-Bi2O3-related phase Bi9ReO17
✍ Scribed by Neeraj Sharma; Ray L. Withers; Kevin S. Knight; Chris D. Ling
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 640 KB
- Volume
- 182
- Category
- Article
- ISSN
- 0022-4596
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A new phase, Bi 13 Mo 4 VO 34 E 13 (E: Bi(III) lone pair) was found in the Bi 2 O 3 -MoO 3 -V 2 O 5 system and its formula determined via single crystal analysis and confirmed by solid state synthesis. It crystallizes in the monoclinic system, space group P2/c, with cell parameters a ؍ 11.652(7) A
The structure of the Fe 2 (Bi 0.69 Sr 2.31 )Fe 2 O 9.5À1/2d has been carried out by single crystal X-ray diffraction. Its structure can be considered as commensurately modulated with a basic structure of Fmmm symmetry and with a modulation vector q ¼ aã à þ gc à whose a and g values are, respectivel