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Structure Cristalline des Complexes du Cuivre(I) Avec la Thiourée III. Complexes Contenant des Cations Cu4 (tu)4 +6 DE TYPE ADAMANTANE: A. LE BIS (BISULFATE) SULFATE D'HEXAKIS (THIOUREE)-TETRACUIVRE(I) MONOHYDRATE Cu4 [SC(NH2) 2] 6 (HSO4) 2SO4.H2O B. LE SULFATE D'HEXAKIS (THIOUREE)-TETRACUIVRE (I) DIHYDRATE Cu4 [SC(NH2) 2] 6 (SO4) 2 · 2H2O

✍ Scribed by M. van Meerssche; R. Kamara; G. Germain; J. P. Declercq

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
503 KB
Volume
91
Category
Article
ISSN
0037-9646

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Structure de Complexes du Cuivre(I) Avec
Structure de Complexes du Cuivre(I) Avec la Thiourée: II. - Sulfate D'Hexakis (Thiourée)-Dicuivre (I) Monohydrate Cu2 [SC (NH2) 2] 6SO4. H2O
✍ M. van Meerssche; R. Kamara; J. P. Declercq; G. Germain 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 284 KB 👁 1 views

## Abstract The title compound is a new Cu(I)‐thiourea complex containing binuclear cyclic cations (Cu~2~tu~6~)^2+^ wich, contrary to other similar knew compounds, exhibits a non‐centrosymmetrical configuration. Crystal data are as follow: orthorhombic, __Pbca__, a = 19.251(7), b = 12.309(2), c = 2