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Structure and Transformations of 1-Alkyladamantane Radical-Cations

โœ Scribed by T. E. Shubina; P. A. Gunchenko; A. G. Yurchenko; P. R Schreiner; E. D. Butova; A. A. Fokin


Book ID
110335578
Publisher
Springer
Year
2002
Tongue
English
Weight
117 KB
Volume
38
Category
Article
ISSN
0040-5760

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The persistence of alkyl substituted cyclobutadiene radical cations strongly depends on the method of generation and the size of the alkyl substituents used. Hindered rotation, the consequence of bulky substituents, is observed in the title compounds. Cyclobutadiene radical cations are transient spe