## Abstract We have investigated how the non‐zwitterionic and zwitterionic structures of aliphatic‐only tripeptides affect the formation and dissociation of peptide radical cations in the gas phase. The non‐zwitterionic forms of the aliphatic‐only peptides in their metal complexes play an important
✦ LIBER ✦
The formation and structure of radical cations
✍ Scribed by J. van Thuijl; J. J. van Houte; A. Maquestiau; R. Flammang; C. de Meyer
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 425 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1076-5174
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## Abstract For Abstract see ChemInform Abstract in Full Text.
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## Abstract The structure and reactivity of the cysteine methyl ester radical cation, CysOMe^.+^, have been examined in the gas phase using a combination of experiment and density functional theory (DFT) calculations. CysOMe^.+^ undergoes rapid ion–molecule reactions with dimethyl disulfide, allyl
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