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Structure and reactivity relations in chromium carbonyl photoassisted hydrogenation of 1,3-dienes

✍ Scribed by Wrighton, Mark.; Schroeder, Mark A.


Book ID
126435985
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
247 KB
Volume
95
Category
Article
ISSN
0002-7863

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The acid-catalysed hydrolysis and alcohol addition of cis-and trans-1-ethoxybuta-1,3dienes have been investigated. It was found by product analyses with deuterium incorporation experiments that in both the reactions the cis isomer protonates at the 2-position as well as at the 4-position while the t