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Abnormally high reactivity of the vinyl hydrogen toward singlet oxygen in twisted 1,3-diene

โœ Scribed by Hajime Mori; Keiichi Ikoma; Yukio Masui; Sachihiko Isoe; Kazuo Kitaura; Shigeo Katsumura

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
262 KB
Volume
37
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Abnormally High Reactivity of the Vinyl Hydrogen Toward Singlet Oxygen in a Twisted 1,3-Diene.
โœ H. MORI; K. IKOMA; Y. MASUI; S. ISOE; K. KITAURA; S. KATSUMURA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 1 views

Abnormally High Reactivity of the Vinyl Hydrogen Toward Singlet Oxygen in a Twisted 1,3-Diene. -Sensitized photooxidation of the twisted 1,3-dienes (I) results in formation of the allene via ene-reaction of the C-7 vinyl hydrogen together with the exo-methylene compounds (III) via reaction of the C