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Structure and reactivity of thiosulfonic acids and their anions: A theoretical study

✍ Scribed by Marek Cypryk; Grzegorz Krasiński; Marian Mikołajczyk

Book ID
112096395
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
321 KB
Volume
23
Category
Article
ISSN
1042-7163

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Substituent effect on electron affinity, gas-phase basicity, and structure of monosubstituted propynyl radicals and their anions: A theoretical study
✍ Gab-Yong Lee 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 484 KB

## Abstract The substituent effect of electron‐withdrawing groups on electron affinity and gas‐phase basicity has been investigated for substituted propynl radicals and their corresponding anions. It is shown that when a hydrogen of the α‐CH~3~ group in the propynyl system is substituted by an elec