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A hydrogen NMR study of some carboxylic acids and their anions

โœ Scribed by K.B Dillon; M.R Harrison; F.J.C Rossotti

Publisher
Elsevier Science
Year
1980
Weight
585 KB
Volume
39
Category
Article
ISSN
0022-2364

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Proton (deuteron) transfer ofhydrogen bonds in benzoic, glutark and pformylbenzoic acids was studied by proton (deuteron) T, measurements. Deuteration of carboxylic protons was found to increase the barriers to classical proton jumping as well as quantum-mechanical tunneling. The former barriers inc