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Structure and properties of the products of reaction between molecular oxygen and new salts of pentacyanocobaltate (II) anion

โœ Scribed by G. A. Kozlov; V. V. Zhilinskaya; K. B. Yatsimirskii


Book ID
112368575
Publisher
Springer
Year
1982
Tongue
English
Weight
504 KB
Volume
17
Category
Article
ISSN
0040-5760

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Spectrophotometric study of the reaction
โœ Riccarda Antiochia; Silvia Canepari; Vincenzo Carunchio ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Springer ๐ŸŒ English โš– 498 KB

The influence of pH and ligand structure on the reaction of cobalt(II) complexes with various dipeptides and molecular oxygen was examined. The minimum pH value required for the formation of dioxygen adducts was found to be about 6.5. This value should be related to amidic deprotonation of dipeptide