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TTF based molecular magnets: Structural and physical properties of new salts involving the [Cr(NCS)4(phen)]− anion

✍ Scribed by D. Le Pevelen; S.S. Turner; P. Day; Keith Prout


Book ID
117538040
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
521 KB
Volume
121
Category
Article
ISSN
0379-6779

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New Molecular Charge Transfer Salts of B
✍ Scott S. Turner; Peter Day; Thomas Gelbrich; Michael B. Hursthouse 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 341 KB

Two new charge transfer salts of BEDT-TTF, bis (ethylenedithio) tetrathiafulvalene, with thiocyanato-metal complex anions have been synthesized and characterized as (BEDT-TTF) 4 [Fe(NCS) 6 ] ' CH 2 Cl 2 and (BEDT-TTF) 2 [Cr(NCS) 4 (bipym)] ' 0.15H 2 O, where bipym ‫؍‬ 2,2-bipyrimidine. The Fe salt,