Structure and properties of pyrolytic carbons prepared in a fluidized bed between 1900° and 2400°C
✍ Scribed by R.J. Price; J.C. Bokros; K. Koyama; J. Chin
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- English
- Weight
- 1003 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0008-6223
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✦ Synopsis
Pyrolytic
carbon deposits were produced in a fluidized bed between 1900" and 2400°C from a carrier gas containing between 1 o/0 and 15 o/0 methane. The carbons had either a 'granular', 'laxninar' or 'isotropic' microstructure. Formation of "granular" carbon occurred at low methane partial pressures and low bed surface areas. Increasing the deposition temperature decreased the metallographic grain size and increased the density, X-ray apparent crystallite size, and preferred orientation of the granular deposits so that at the highest temperature, the deposits took on a laminar appearance. Increasing the deposition temperature increased the crystallite size and density of the isotropic and transition deposits. The elastic moduli and fracture stresses of the carbons deposited from 3% methane rose from 1.5 to 1.8~ 10s psi and 18 to 32X lOa psi, respectively, as the deposition temperature was increased from 1900" to 2400°C. The isotropic and transition carbons had fracture stresses of -30x lo* psi and elastic moduli that decreased from ~2.2 to -1.6~ lOa psi over the deposition temperature range of 1900" to 2400°C. The carbons had thermal conductivities perpendicular to the deposition plane in the range of 1 to 6 x 1O-a Cal/cm set "C. The conductivities were highest for the isotropic carbons and lowest for the most highly oriented laminar carbons. The relations between deposition conditions, structure, and properties are discussed.
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