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Structure and Properties of 2,2-Dibromovinyl Trifluoromethyl Ketone.

✍ Scribed by G. V. Bozhenkov; Yu. L. Frolov; D. S.-D. Toryashinova; G. G. Levkovskaya; A. N. Mirskova

Publisher: John Wiley and Sons
Year: 2004
Weight: 96 KB
Volume: 35
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200429080

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## Abstract The acid‐catalyzed cyclization‐condensation between anilines and ethyl 4,4,4‐trifluoroacetoacetate affords 1,4‐dihydro‐2‐trifluoromethyl‐4__H__‐4‐quinolinones (**1**), which can easily be converted into 4‐bromo‐2‐(trifluoromethyl)quinolines. These undergo halogen/metal exchange, generat