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Structure and Picosecond Excited-States Dynamics in Isolated, Supercooled 4-( N , N -Dimethylamino)benzonitrile

✍ Scribed by Pérez Salgado, F.; Herbich, J.; Kunst, A. G. M.; Rettschnick, R. P. H.


Book ID
125986282
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
108 KB
Volume
103
Category
Article
ISSN
1089-5639

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✍ O. Kajimoto; T. Nayuki; T. Kobayashi 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 325 KB

The rate of formation of the intramolecular charge-transfer state of 4-(N,N-dimethylamino)benzonitrile (DMABN) has been determined in supercritical CFsH using a fast single-photon counting technique. The rate constant increases rapidly with increasing CFIH density, indicating the importance of the p