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Ab Initio Study of the Electronic Excited States in 4-( N , N -Dimethylamino)benzonitrile with Inclusion of Solvent Effects: The Internal Charge Transfer Process

✍ Scribed by Mennucci, Benedetta; Toniolo, Alessandro; Tomasi, Jacopo


Book ID
125509163
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
425 KB
Volume
122
Category
Article
ISSN
0002-7863

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The rate of formation of the intramolecular charge-transfer state of 4-(N,N-dimethylamino)benzonitrile (DMABN) has been determined in supercritical CFsH using a fast single-photon counting technique. The rate constant increases rapidly with increasing CFIH density, indicating the importance of the p