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Structure and magnetic properties of LiMVO4(M = Co, Ni, Cu) spinels

✍ Scribed by C. González; M. Gaitán; M. L. López; M. L. Veiga; R. Saez-Puche; C. Pico

Publisher
Springer
Year
1994
Tongue
English
Weight
247 KB
Volume
29
Category
Article
ISSN
0022-2461

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The compounds CuCr 2 O 4 and NiCr 2 O 4 crystallize at room temperature in a tetragonal distorted spinel structure, s.g. I4 1 /amd, with axes ratio c/ao1 and 41, respectively. The distortion is caused by the Jahn-Teller ions Cu 2+ and Ni 2+ which flatten or elongate their surrounding oxygen tetrahed