Structure and Kinetics of Oxidation of Amphiphilic Nickel(II) Pentaazamacrocycles by Peroxodisulfate and by a Nickel(III) Pendant-Arm Macrocycle
β Scribed by Robert I. Haines; James E. Rowley
- Book ID
- 111589580
- Publisher
- Springer Netherlands
- Year
- 2003
- Tongue
- English
- Weight
- 122 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0923-0750
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π SIMILAR VOLUMES
The kinetics of the oxidation of thiosulfate ion by [Mn(Y)I ~ (H4Y = trans-cyclohexane-l,2-diamine-N,N,N',N'-tetraacetic acid) and [Ni(L1)I2+ (HL1 = 15-amino-3-methyl-4,7,10,13-tetraazapentadec-3-en-2one oxime) have been investigated at 20.0, 30.0, and 40.0"C in aqueous solution and found to follow
The kinetics of the oxidation of formate, oxalate, and malonate by [Ni III (L 1 )] 2Ο© (where HL 1 Ο 15-amino-3-methyl-4,7,10,13-tetraazapentadec-3-en-2-one oxime) were carried out over the regions pH 3.0 -5. 75, 2.80 -5.50, and 2.50 -7.58, respectively, at constant ionic strength and temperature 40Π