A new ligand that facilitates samarium diiodide-mediated reductions has been developed. Addition of a solution of samarium diiodide to the dehydro dimer of hexamethylphosphoramide results in a purple complex which is an excellent reductant for a variety of organic functionalities. The complex was ch
✦ LIBER ✦
Structure and Energetics of the Samarium Diiodide−HMPA Complex in Tetrahydrofuran
✍ Scribed by Shotwell, J. Brad; Sealy, Jennifer M.; Flowers, Robert A.
- Book ID
- 120938744
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 57 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0022-3263
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