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Characterization of the complex formed between samarium diiodide and the dehydro dimer of HMPA (diHMPA)

✍ Scribed by Chriss E. McDonald; Jeremy D. Ramsey; James A. Grant; Kelly A. Howerter

Book ID: 104096759
Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 217 KB
Volume: 50
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2009.06.139

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✦ Synopsis

A new ligand that facilitates samarium diiodide-mediated reductions has been developed. Addition of a solution of samarium diiodide to the dehydro dimer of hexamethylphosphoramide results in a purple complex which is an excellent reductant for a variety of organic functionalities. The complex was characterized by the kinetics of reduction of 1-bromodecane, visible spectroscopy, and cyclic voltammetry.

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