Structure and Dynamics of the Aluminum Chlorohydrate Polymer Al13O4(OH)24 (H2O)12Cl7.
β Scribed by Vojislava Pophristic; Venkatachalapathy S. K. Balagurusamy; Michael L. Klein
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 56 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A basic aluminium chloride with high chlorine content (basicity 1.85) has been crystallized from a concentrated aqueous solution. Its crystal structure has been determined by X-ray structure analysis. The structure contains
The synthesis of [Al 13 O 4 (OH) 24 (H 2 O) 12 ] x MS 2 (x β«Ψβ¬ 0.02-0.05, M β«Ψβ¬ Mo; x β«Ψβ¬ 0.02-0.055, M β«Ψβ¬ W) was accomplished by a precipitative encapsulation technique using single layers of MS 2 . The products were characterized by powder X-ray diffraction, energy dispersive spectroscopy (EDS),
The preparation of complex 1 . ~~4 and its crystal structure analysis have both been reported [S.Xl. The synthesis of the N-methylated nickel chelates roc-5.6 will be reported at a later date. In contrast to ruc-4[8], rw-5,6 are 1101 oxygen-sensitive. ## Cation Inclusion within the Mixed-Valence