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Structure and Dynamics of Lanthanide(III) Complexes with an N-Alkylated do3a Ligand (H3do3a = 1,4,7,10-Tetraazacyclododecane-1,4,7-triacetic Acid): A Combined Experimental and DFT Study

✍ Scribed by Martín Regueiro-Figueroa; David Esteban-Gómez; Andrés de Blas; Teresa Rodríguez-Blas; Carlos Platas-Iglesias


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
554 KB
Volume
2010
Category
Article
ISSN
1434-1948

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The hydration state of a series of [Ln(DO2A)(H 2 O) n ] + complexes in aqueous solution at pH = 6.4-7.0 was studied by measuring the lanthanide-induced 17 O shifts (LIS) of water [Ln includes elements from Ce to Yb; DO2A = 1,7-bis(carboxymethyl)-1,4,7,10-tetraazacyclododecane]. Their contact contrib