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Lanthanide(III) Complexes of 4,10-Bis(phosphonomethyl)-1,4,7,10-tetraazacyclododecane-1,7-diacetic acid (trans-H6do2a2p) in Solution and in the Solid State: Structural Studies Along the Series

✍ Scribed by M. Paula C. Campello; Sara Lacerda; Isabel C. Santos; Giovannia A. Pereira; Carlos F. G. C. Geraldes; Jan Kotek; Petr Hermann; Jakub Vaněk; Přemysl Lubal; Vojtěch Kubíček ; Éva Tóth; Isabel Santos

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 549 KB
Volume: 16
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201000320

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The hydration state of a series of [Ln(DO2A)(H 2 O) n ] + complexes in aqueous solution at pH = 6.4-7.0 was studied by measuring the lanthanide-induced 17 O shifts (LIS) of water [Ln includes elements from Ce to Yb; DO2A = 1,7-bis(carboxymethyl)-1,4,7,10-tetraazacyclododecane]. Their contact contrib