Structure and Bonding in Cyclic Sulfur-Nitrogen Compounds
✍ Scribed by Prof. Dr. Herbert W. Roesky
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 556 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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The new compound C 10 H 6 P(S)[NSi(CH 3 ) 3 ] 2 P(S) (3) which contains a P 2 N 2 heterocycle has been prepared in low yield by partial thermal decomposition of 1 3 )SP(S) 2 ] ± (2). Reaction of 2 with potassium hydroxide in acetonitrile gives the completely desilylated product 4). The structures o
line. Since the intercept of I/@,,, GS 1/[A] is not unity the concentration quenching process (kcQ) must be important. This may suggest an excimer intermediate but our kinetic data does not demand this intermediate. anion (6-9 nm)r71 should place the lowest excited singlet state of the acid below t