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Structure Analysis of a Transient Triplet Carbene Trapped in a Crystal

โœ Scribed by Kawano, Masaki; Hirai, Katsuyuki; Tomioka, Hideo; Ohashi, Yuji


Book ID
127008570
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
131 KB
Volume
123
Category
Article
ISSN
0002-7863

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The sign of D in the triplet carbene of
โœ R. Huber; M. Schwoerer; C. Bubeck; H. Sixl ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 319 KB

The sign of the zero field splitting parameter D of a triplet carbene in partially polymerized poly-[1.2-bis-Cptolylsulfonyloxymethylen)-I-buten-3-inylen] (ITS) has been determined from the temperature dependence of the ESR intensities to be positive.