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Structural studies of the capsular antigen of haemophilus infuenzae type c

✍ Scribed by Paula Branefors-Helander; Björn Classon; Lennart Kenne; Bengt Lindberg

Book ID
102639319
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
418 KB
Volume
76
Category
Article
ISSN
0008-6215

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✦ Synopsis

The structure of the capsular antigen from Haemophilus influenzae type c has been investigated, n.m.r. spectroscopy being the principal method used. It is concluded that the antigen is composed of repeating-units having the following structure: formula: (see text). O-Acetyl groups are present in approximately 90% of the repeating-units.

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The repeating units 2-O-beta-D-glucopyranosyl-L-ribitol 4'- and 1-phosphate of Haemophilus influenzae type a capsular antigen have been synthesised by condensation of an alpha-D-glucopyranosyl bromide derivative with 5-O-allyl-1,2,3-tri-O-benzyl-D-ribitol followed by selective deprotection of HO-4'