Structural studies of carbanionic species formed from phosphonates: anions of diethyl benzyl- and cyanomethylphosphonates
β Scribed by Bottin-Strzalko, Tekla; Seyden-Penne, Jacqueline; Pouet, Marie-Jose; Simonnin, Marie Paule
- Book ID
- 118132824
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 740 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The structure of the carbanionic species 4 formed from diethyl(2βoxopropyl)phosphonate and __t__βBuOK has been studied by ^1^H, ^13^C and ^31^P NMR. In an associating medium (pyridine), a single chelated (C) carbanionic species 4__Z__ (C) is observed. Two slowly interconverting species
CV4 7AL, UK [C4HsN]+' ions have been generated from eleven neutral species. From 'a study of their metastable transitions and the translational energy released in the fragmentation in which CzHz B lost, it is concluded structures when they are generated from motonitrile, allyl cyanide, cydopropyl cy