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Structural studies of carbanionic species formed from phosphonates: anions of diethyl benzyl- and cyanomethylphosphonates

✍ Scribed by Bottin-Strzalko, Tekla; Seyden-Penne, Jacqueline; Pouet, Marie-Jose; Simonnin, Marie Paule


Book ID
118132824
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
740 KB
Volume
43
Category
Article
ISSN
0022-3263

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Structural studies of carbanionic specie
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## Abstract The structure of the carbanionic species 4 formed from diethyl(2‐oxopropyl)phosphonate and __t__‐BuOK has been studied by ^1^H, ^13^C and ^31^P NMR. In an associating medium (pyridine), a single chelated (C) carbanionic species 4__Z__ (C) is observed. Two slowly interconverting species

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