A study of the structures of decomposing and non-decomposing [C4H5N]+˙ ions formed from different neutral species
✍ Scribed by H. Sakurai; K. R. Jennings
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 463 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1076-5174
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✦ Synopsis
CV4 7AL, UK [C4HsN]+' ions have been generated from eleven neutral species. From 'a study of their metastable transitions and the translational energy released in the fragmentation in which CzHz B lost, it is concluded structures when they are generated from motonitrile, allyl cyanide, cydopropyl cyanide, methacrylonitrile, pyrrole, 2-, 3-and 4-hydroxypyridines and 2-aminopyridine. The [C4HsN]+' ions formed from allyl isocyanide decompose from a different structure and those given by cydopropyl isocyanide appear to decompose from a mixture of the two structures. Non-decomposing [C4HsN]+' ions were investigated by means of their collaion induced decomposition spectra using a B/E linked scan. Six Merent structures or mixtures of structures are suggested to explain these observations. that [C4HsN]+' ions with smcient energy to decompose do so from a common structure or mixture of