The structural determination of reaction intermediates in organophosphonate anion chemistry has been stimulated by the extraordinary synthetic utility of these reagents. A great body of information about the solid-state and solution structures of phosphorus-stabilized anions has been collected duri
Structural Properties of Phosphorus Oxides in the Solid Aggregation State
✍ Scribed by Prof. Dr. Martin Jansen; Dipl.-Chem. Marlen Voss; Dr. Hans-Jörg Deiseroth
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 138 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0044-8249
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Diphenyl diselenide reacts with [CpRh(CO) 2 ] (1) to give the dimer [CpRh(SePh)(l-SePh)] 2 (2), the solid state structure of which has been determined by X-ray analysis; the dimeric structure is retained in solution. In contrast, [Cp\*Rh(CO) 2 ] (4) gives the ionic product [Cp\*Rh(l-SePh) 3 RhCp\*][