Structural, Magnetic, and Ion-Exchange Properties of a New Layered Alkaline/Alkaline Earth Iron Phosphate: NaBaFe 4 (HPO 4 ) 3 (PO 4 ) 3 ·H 2 O
✍ Scribed by Korzenski, Michael B.; Kolis, Joseph W.
- Book ID
- 125549849
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 110 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0020-1669
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Two new potassium vanadium phosphates have been prepared and their structures have been determined from analysis of single crystal X-ray data. The two compounds, \(\mathrm{K}_{3}(\mathrm{VO})\left(\mathrm{V}_{2} \mathrm{O}_{3}\right)\) \(\left(\mathrm{PO}_{4}\right)_{2}\left(\mathrm{HPO}_{4}\right)\
The solution-phase synthesis, single crystal structure, and some physical properties of CN 3 H 6 • VO(H 2 O)(HPO 4 ) (H 2 PO 4 ) • H 2 O, a new guanidinium vanadium (IV) hydrogen phosphate hydrate, are reported. This phase is built up from one-dimensional chains of VO 5 (H 2 O) octahedra and (H 2 /H