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Structural investigation of tetraperoxo complexes of Mo(VI) and W(VI): X-ray and theoretical studies

✍ Scribed by M. Grzywa; W. Łasocha; D. Rutkowska-Żbik

Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
780 KB
Volume
182
Category
Article
ISSN
0022-4596

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Oxidation of N,N-benzylalkylamines to nitrones by Mo(VI) and W(VI) polyperoxo complexes
✍ Francesco Paolo Ballistreri; Elena Barbuzzi; Gaetano Andrea Tomaselli; Rosa Mari 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 666 KB

Oxidation of N,N-benzylalkylamines in chloroform by Mo(VI) and W(VI) polyperoxo complexes (PPC) of general formula Q~{P0,[M0(02)2],}'-(Q'= onium ion) yield the corresponding nitrones as oxidized products quantitatively. Only in the case of N,N-benzylmethylamine the formation of nitrone is accompanie