The 16-electron, five-coordinate fluoro complex [RuF(dppp) 2 ]PF 6 (1a; dppp propane-1,3-diylbis[diphenylphosphine] smoothly reacts with 1,3-diphenylallyl bromide ( 1,1'-(3-bromoprop-1-ene-1,3-diyl)bis[benzene]) in dry CDCl 3 to give 1,3-diphenylallyl fluoride and [RuBr(dppp) 2 ] in nearly quantitat
Structural Investigation in Solution of a Series of Five-Coordinate Bisphosphanylaryl Ruthenium(II) Complexes
✍ Scribed by Paulo Dani; Gerard P. M. van Klink; Gerard van Koten
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 273 KB
- Volume
- 2000
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Five-coordinate complexes [PtX 2 (olefin)(2,9-Me 2 -phen)] (1; chloride ions in axial positions. The iodo complexes 1(a-c)z are not oxidized by iodine even under UV irradiation but 2,9-Me 2 -phen = 2,9-dimethyl-1,10-phenanthroline; olefin = ethene denoted by a, propene by b, 1-butene by c; X = Cl re
The dizinc(II) bispyridylporphyrin ruthenium complex trans,cis,cis[RuCl2(CO)2(Zn.4'-cisDPyP)2] (1Zn, 4'-cisDPyP = 5,10-bis(4'-pyridyl)-15,20-diphenylporphyrin) features two donor (the uncoordinated 4'-N(py) atoms) and two acceptor (the Zn atoms) sites and is thus a building block suited for two-poin
O-bonded amide complexes of platinum(II), which are stable species due to the higher affinity of platinum for nitrogen donors. In contrast O-bonded amides owe their stability to in acetone solution and which undergo solvolysis in neat water with a rate constant as slow as 8.7•10 -5 s -1 , are their