Neutron diffraction studies on liquid carbon tetrachloride have been carried out under pressures of 1.0 bar and 3.5 kbar. The pressure effect on the liquid structure results in a shift of the three peaks of the corrected coherent differential scattering cross-section, two towards higher x-values and
Structural features of liquid CCl4 in porous silica
β Scribed by J.C. Dore; M. Dunn; M.-C.Bellisent Funel
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 313 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Neutrondiffraction studies have been made for liquid CCL, m a porous silica (Spherisorb S2OW) with a pore size of z 90 A diameter. The resulting intensity pattern exhibits the expected "diffraction broadening" of the main peak but also shows an apparent change in the local uttermolecular correlations. Although this effect is small, it varies systematically with the degree of coverage and suggests that the proximity of the interface affects the interlocking of neighbouring molecules.
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