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Structural features and NMR195Pt spectroscopy of cooperite monocrystals (natural Pts)

✍ Scribed by A. V. Ivanov; V. I. Palazhchenko; V. E. Strikha; O. N. Antzutkin; W. Forsling


Book ID
110203792
Publisher
SP MAIK Nauka/Interperiodica
Year
2006
Tongue
English
Weight
205 KB
Volume
410
Category
Article
ISSN
1028-334X

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195Pt-NMR Spectroscopy of Catalytically
✍ Dr. Karl-H. A. Ostoja Starzewski; Dr. Paul S. Pregosin πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 237 KB

**An extremely high coupling constant of 28954 Hz** (^1^__J__(^195^Pt^119^Sn))β€”the highest one‐bond spin‐spin coupling yet foundβ€”has been measured for [PtCl(SnCl~3~)(PEt~3~)~2~]. In combination with SnCl~2~, platinum‐phosphane complexes are excellent homogeneous catalysts for hydrogenation and hydro