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Structural factors controlling the aggregation of lithium phenolates in weakly polar aprotic solvents

✍ Scribed by Jackman, Lloyd M.; Smith, B. D.

Book ID
115502680
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
910 KB
Volume
110
Category
Article
ISSN
0002-7863

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The 'Li quadrupole splitting constants [ QSC = (1 + q2/3)"2(e2Qqz,/h)] for di-and tetra-solvated dimeric lithium 2,6-dimethyl-and 2,6-di-tert-butylphenolates were determined from measurements of 'Li and I3C spin lattice relaxation times. After correcting for anisotropic rotational diffusion, the est