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Structural effects on the proton-transfer kinetics of 3-hydroxyflavones

โœ Scribed by Strandjord, Andrew J. G.; Smith, David E.; Barbara, Paul F.

Book ID
115518951
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
610 KB
Volume
89
Category
Article
ISSN
0022-3654

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Hydrogen/deuterium isotope effects on th
Hydrogen/deuterium isotope effects on the excited-state proton transfer kinetics of 3-hydroxyflavone
โœ A.J.G. Strandjord; P.F. Barbara ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 631 KB

The static and transient fluorescence spectroscopy of 3-hydroxyflavone, 3HF, has been investigated as a function of deuteration of the 3-hydroxy group and the solvent. Small H/D isotope effects are observed for at least two of the simple rate constants for the excited-state dynamics. The isotope eff