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Structural Differences between the Closed and Open States of Channelrhodopsin-2 as Observed by Epr Spectroscopy

✍ Scribed by Krause, Nils; Engelhard, Christopher; Heberle, Joachim; Schlesinger, Ramona; Bittl, Robert


Book ID
122216152
Publisher
Biophysical Society
Year
2014
Tongue
English
Weight
164 KB
Volume
106
Category
Article
ISSN
0006-3495

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Rapid exchange of Ca2+ between the bulk
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The rate constant for dissociation of [ Ca(AA-)] +, where (AA-) is the radical anion of ascorbic acid, has been measured by observation of specific line broadening in the ESR spectrum. Its value in DMSO at 298 K is 4.68~ 10' s-'. The mechanism for the line broadening is a combination of a g and a hy