In situ 1 H nuclear magnetic resonance spectroscopy was used to investigate the processes that occur during the synthesis of 1,3,6,8tetraazatricyclo[4.3.1.1 3,8 ]undecane (TATU). NMR analysis showed a reaction mixture containing more than one compound. The production of these intermediates and colla
✦ LIBER ✦
Structural Consequences of Anomeric Effect in 1,3,6,8-tetraazatricyclo[4.3.1.13,8]undecan-1-ium pentachlorophenolate monohydrate
✍ Scribed by Augusto Rivera; John Sadat-Bernal; Jaime Ríos-Motta; Michal Dušek; Karla Fejfarová
- Book ID
- 106404761
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 298 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1572-8854
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The reaction of the cyclic aminal 1,3,6,8-tetraazatricyclo[4.3.1.1 3,8 ]undecane (TATU, 4) with diazonium salts resulted in the formation of a new series of bis-triazenes, namely 3,8-bis [(4-methoxyphenyl) 3,6,8-tetraazabicyclo[4.3.1]decane 6c. When aniline derived diazonium salt 5d was coupled with