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Structural characterization of isomeric triazolocoumarins by high- and low-energy collision spectrometry of M+˙, [M + H]+ and [M − H]− species

✍ Scribed by C. Evans; P. Traldi; A. Chilin; G. Pastorini; P. Rodighiero


Book ID
102965880
Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
576 KB
Volume
26
Category
Article
ISSN
1076-5174

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✦ Synopsis


Abstract

Two monometayl‐ and four dimethyl‐triazolocoumarin isomers were characterized by their electron impact mass spectra and by low‐energy collision experiments performed on molecular ions M^+^˙ and other fragment ions with an ion‐trap mass spectrometer. High‐energy collision‐activated dissociation measurements were performed on the protonated [M + H]^+^ and deprotonated [M − H]^−^ molecular ion obtained by fast atom bombardment and M^+^˙ species produced by electron impact ionization on a double‐focusing, reverse‐geometry instrument. The data obtained allowed unequivocal structural identification of all the compounds investigated.


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