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Structural and electronic consequences of protonation in {Mn4O6}4+ cores: pH dependent properties of oxo-bridged manganese complexes

✍ Scribed by Hagen, Karl S.; Westmoreland, T. David; Scott, Michael J.; Armstrong, William H.


Book ID
121403776
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
400 KB
Volume
111
Category
Article
ISSN
0002-7863

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In aqueous media (pH 2.5 -6.0), the Mn IV tetramer [Mn 4 (m-O) 6 A C H T U N G T R E N N U N G (bipy) 6 ] 4+ (1 4+ ; bipy = 2,2'-bipyridine) oxidizes both glyoxylic and pyruvic acid to formic and acetic acid, respectively, under formation of CO 2 . Kinetics studies suggest that the species 1 4+ , it