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Oxidation of NIII and N–I by an {Mn4O6}4+ Core in Aqueous Media: Proton-Coupled Electron Transfer

✍ Scribed by Suranjana Das; Subrata Mukhopadhyay

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
180 KB
Volume
2007
Category
Article
ISSN
1434-1948

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## Abstract In aqueous media, the Mn^IV^ trimer [Mn^IV^~3~(μ‐O)~4~(phen)~4~(H~2~O)~2~]^4+^ (1, phen = 1,10‐phenanthroline) equilibrates with its deprotonated from [Mn~3~(μ‐O)~4~(phen)~4~(H~2~O)(OH)]^3+^ (2). Among the several synthetic multinuclear oxo‐ and/or carboxylato‐bridged manganese complexe