Structural and electrochemical characterization of the products of the C60?piperazine reaction
โ Scribed by Balch, Alan L.; Cullison, Brian; Fawcett, W. Ronald; Ginwalla, Arwa S.; Olmstead, Marilyn M.; Winkler, Krzysztof
- Book ID
- 121409404
- Publisher
- The Royal Society of Chemistry
- Year
- 1995
- Tongue
- English
- Weight
- 248 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0022-4936
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The 1 H NMR spectrum of the piperazine-C 60 monoadduct has been assigned for the first time almost 10 years after it was synthesised. The preparation and characterisation of the first (C2-substituted piperazine)-C 60 monoadduct are also described, revealing the C2-substituent as occupying an exo pos
High-purity crystals of 99.1% 13C enriched C60 have been produced and their Raman and fluorescence spectra recorded together with those of C60 crystals containing the ~3C isotope in natural abundance. The relative frequency shift of the intramolecular Raman-active modes is found to be determined by