A catecholborane mediated reaction of the lactam epoxide unexpectedly gave the cis-diol a useful intermediate for adenosine agonists. The origin of this reaction is postulated to arise from the formation ofa boronic anhydride which is transferred to the electron deficient C-6 via transannular attack
✦ LIBER ✦
Structural analysis of three methyl N-phosphorylated 5,6-dihydroxy-2-azabicyclo[2.2.1]heptane-3-carboxylates
✍ Scribed by Carlos A.D. Sousa; M. Luísa C. Vale; José E. Rodríguez-Borges; Xerardo Garcia-Mera
- Book ID
- 113806134
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 712 KB
- Volume
- 1007
- Category
- Article
- ISSN
- 0022-2860
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