Infrared fluorescence and double infrared resonance have been used to measure the V-T relaxation of CD3F and CD 4 in mixtures with He, He, At, Kr, Xe and HCI in the gas phase and in the liquid Ar, Kr, Xe. It is shown that the temperature dependence of V-T probabilities in the interval 350-150ยฐK can
โฆ LIBER โฆ
Strong Interactions in gas phase reactions: The F + HN3 system
โ Scribed by J.J. Sloan; D.G. Watson; J.S. Wright
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 652 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0301-0104
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The reaction rates of SO3 with CH,OH in He were measured at total pressures of 0.7-1.6 torr in flow tubes. The concentration of SO3 was monitored by the SOz\* fluorescence from excitation of SO3 at 147 nm. The reaction rate constant of SO3 + CH30H in the gas phase is determined to be (1.17 ? 0.16) x