𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stretch-Bend Levels of Acetylene: Analysis of the Hot Bands in the 3800 cm−1 Region

✍ Scribed by Y.A. Sarma; R. Dcunha; G. Guelachvili; R. Farrenq; K.N. Rao

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
587 KB
Volume
173
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

The high-resolution FTIR spectrum of acetylene in the (\sim 3800 \mathrm{~cm}^{-1}) region has been analyzed for various hot bands originating from the low-lying (v_{4}) and (v_{5}) bending modes. The data have been fitted to a second-order transformed Hamiltonian which includes appropriate off-diagonal terms to account for vibrational and rotational (l)-type resonances. Parameters for various stretchbend combination levels, which fit the data with residuals (\left(\sim 2.5 \times 10^{-4} \mathrm{~cm}^{-1}\right)) approaching the experimental accuracy, are reported. c 1995 Academic Press, Inc.

📜 SIMILAR VOLUMES

Fermi Coupling and l-Type Resonance Effe
Fermi Coupling and l-Type Resonance Effects in the Hot Bands of Acetylene: The 2650-cm−1 Region
✍ R. Dcunha; Y.A. Sarma; V.A. Job; G. Guelachvili; K.N. Rao 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 488 KB

The hot bands originating from the low-lying \(\nu_{4}\left(I_{g}\right)\) state to the \(\nu_{3}\left(\Sigma_{u}^{+}\right)\)fundamental and ( \(\nu_{2}\) \(\left.+v_{4}+v_{5}\right)^{2,0 \pm}\left(\Sigma_{u}^{+}, \Sigma_{u}^{-}, \Delta_{u}^{e / /}\right)\) combination states of acetylene have been

First Study of thev2= 3 Dyad {(130), (03
First Study of thev2= 3 Dyad {(130), (031)} of Ozone through the Analysis of Hot Bands in the 2300–2600 cm−1Region
✍ A. Barbe; S. Mikhailenko; J.J. Plateaux; Vl.G. Tyuterev 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 130 KB

Hot bands nu1 + 3nu2 - nu2 and 3nu2 + nu3 - nu2 of 16O3 in the region 2300-2600 cm-1 and the cold band 3nu2 + nu3 in the region 3050-3110 cm-1, corresponding to the v2 = 3 dyad {(130), (031)}, have been observed for the first time, using the Fourier Transform Spectrometer (FTS) at Reims and the usua

High-Resolution Infrared Study of the Ho
High-Resolution Infrared Study of the Hot Bands in the Region of the Bending Fundamental ν4of HCCI
✍ Anne-Maaria Tolonen 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 268 KB

The hot band structure of the high-resolution Fourier transform spectra of monoiodoacetylene measured in the region of the bending fundamental n 1 4 (600-655 cm 01 ) with a resolution of 0.0020 cm 01 has been studied in detail. In addition, three spectra n 4 / n 5 0 n 4 (180-320 cm 01 ), 2n 0 4 (122

Emission Spectrum of Hot HDO in the 380–
Emission Spectrum of Hot HDO in the 380–2190 cm−1 Region
✍ T. Parekunnel; P.F. Bernath; N.F. Zobov; S.V. Shirin; Oleg L. Polyansky; Jonatha 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 84 KB

Fourier transform emission spectra were recorded using a mixture of H 2 O and D 2 O at a temperature of 1500 • C. The spectra were recorded in three overlapping sections and cover the wavenumber range 380-2190 cm -1 . A total of 22 106 lines were measured, of which 60% are thought to belong to HDO.