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Strecker-type Degradation of Phenylalanine by Methyl 9,10-Epoxy-13-oxo-11-octadecenoate and Methyl 12,13-Epoxy-9-oxo-11-octadecenoate

✍ Scribed by Zamora, Rosario; Gallardo, Emerenciana; Navarro, José L.; Hidalgo, Francisco J.

Book ID
126772718
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
88 KB
Volume
53
Category
Article
ISSN
0021-8561

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Syntheses and reactions of methyl (Z)-9,10-epoxy-13-oxo-(E)-11-octadecenoate and methyl (E)-9,10-epoxy-13-oxo-(E)-11-octadecenoate
✍ F.J. Hidalgo; R. Zamora; E. Vioque 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 527 KB

The syntheses and reactions of two epoxyketoacids (methyl (Z)-9,10-epoxy-13-oxo-(E)-II-octadecenoate (IV) and methyl (E)-9,10-epoxy-13-oxo-(E)-ll-octadecenoate (V)) are described. The synthetic method is based on the stereoselective oxidation of linoleic acid by soybean lipoxygenase to produce the c