Volatiles from thermal decomposition of isomeric methyl (12S, 13S)-(E)-12,13-epoxy-9-hydroperoxy-10-octadecenoates
โ Scribed by H. W. Gardner; E. Selke
- Book ID
- 112774839
- Publisher
- Springer-Verlag
- Year
- 1984
- Tongue
- English
- Weight
- 453 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0024-4201
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๐ SIMILAR VOLUMES
A solution of methyl 13(S)-hydroperoxy-9(Z),ll(E)-octadecadienoate (13-HPOD)in methanol was irradiated under anaerobic conditions at 15ยฐC with light at wavelengths greater than 230 nm. After 2 h the 13-HPOD was completely degraded and four major products were formed. Three of them were identified as
in the presence of oxygen, UV-irradiation of a solution of methyl 13(S)-hydroperoxy-9(Z),l I(E)octadecadienoate (13-HPOD) in methanol yields stereoisomers of methyl 9,13-dihydroxy-10methoxy-1 l(E)-octadecenoate and methyl 9,13-dihydroxy-12-methoxy-10(E)-octadecenoate as major products. The reaction