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Strained ring systems. VIII. Alternate synthesis of 2-oxy derivatives of bicyclo[2.2.0]hexane and the rearrangement of endo-bicyclo[2.2.0]hex-2-yl acetate

✍ Scribed by McDonald, Richard N.; Davis, Gerald E.

Book ID: 126064237
Publisher: American Chemical Society
Year: 1969
Tongue: English
Weight: 821 KB
Volume: 34
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01258a086

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The photosensitized rearrangement of ary

The photosensitized rearrangement of aryl-substituted tricyclo[2.2.0.02,6]hexanes to bicyclo[3.1.0]hex-2-enes

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The triplet sensitized irradiation of 3-allyl-diaryl-substituted cyclopropenes to m.l.O]hex-2-enes proceeds via an intramolecular [2+2]-cycloaddition followed by a subsequent rearrangement of the initially formed tricycl0[2.2.0.0~~~]hexane skeleton. Previous work from this laboratory has shown that